The title compound, C19H18O3, crystallizes with three mol-ecules (A, B and C) in the asymmetric unit. The carbonyl O atom shows positional disorder over two sites in mol-ecules A and B; the site-occupancy ratios are 0.76 (3):0.24 (3) and 0.86 (3):0.14 (3), respectively. The ethyl-ene fragments in each mol-ecule have an E conformation, while the C-O-C-C torsion angles indicate near planarity. The dihedral angles formed by the aromatic rings are 20.0 (1), 23.7 (1) and 16.1 (1)° for mol-ecules A, B and C, respectively. Intra-molecular C-H⋯O hydrogen bonds occur in each mol-ecule.

Download full-text PDF

Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588484PMC
http://dx.doi.org/10.1107/S1600536813000299DOI Listing

Publication Analysis

Top Keywords

3e-1116-dioxatricyclo-[15400510]henicosa-12135791719-heptaen-2-one title
4
title compound
4
compound c19h18o3
4
c19h18o3 crystallizes
4
crystallizes three
4
three mol-ecules
4
mol-ecules asymmetric
4
asymmetric unit
4
unit carbonyl
4
carbonyl atom
4

Similar Publications

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!