2-(4-Oxo-3-phenyl-1,3-thia-zolidin-2-yl-idene)malononitrile.

Acta Crystallogr Sect E Struct Rep Online

Department of Chemistry, American University in Cairo, PO Box 74, New Cairo 11835, Egypt.

Published: March 2013

In the title compound, C12H7N3OS, the essentially planar thia-zole ring (r.m.s. deviation = 0.022 Å) forms dihedral angles of 84.88 (9) and 1.8 (3)° with the phenyl ring and the -C(CN)2 group (r.m.s. deviation = 0.003 Å), respectively. The mol-ecule has approximate local Cs symmetry. In the crystal, molecules are linked via C-H⋯N hydrogen bonds, forming chains propagating along [101]. The crystal studied was found to be an inversion twin with a refined 0.63 (1):0.37 (1) domain ratio.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588553PMC
http://dx.doi.org/10.1107/S160053681300216XDOI Listing

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