Bis(azido-κN)bis-[4-(dimethyl-amino)-pyridine-κN]zinc.

Acta Crystallogr Sect E Struct Rep Online

Unité de Recherche de Chimie de l'Environnement et Moléculaire Structurale (CHEMS), Faculté des Sciences Exactes, Campus Chaabet Ersas, Université Constantine I, 25000 Constantine, Algeria.

Published: March 2013

In the title complex, [Zn(N3)2(C7H10N2)2], the Zn(II) atom is coordinated by two N atoms from two 4-(dimethyl-amino)-pyridine (DMAP) ligands and by two N atoms from two azide anions in a distorted tetra-hedral coordination geometry. In the crystal, weak C-H⋯N hydrogen bonds between the DMAP and azide ligands link these discrete complex mol-ecules into a three-dimensional supra-molecular network.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588442PMC
http://dx.doi.org/10.1107/S1600536813004686DOI Listing

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