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2-(1-Phenyl-1H-benzimidazol-2-yl)phenol. | LitMetric

2-(1-Phenyl-1H-benzimidazol-2-yl)phenol.

Acta Crystallogr Sect E Struct Rep Online

Postgraduate Research Department of Physics, Rajah Serfoji Government College (Autonomous), Thanjavur 613 005, Tamilnadu, India.

Published: January 2013

In the title mol-ecule, C19H14N2O, the benzimidazole unit is close to being planar [maximum deviation = 0.0253 (11) Å] and forms dihedral angles of 68.98 (6) and 20.38 (7)° with the adjacent phenyl and benzene rings; the dihedral angle between the latter two planes is 64.30 (7)°. An intra-molecular O-H⋯N hydrogen bond generates an S(6) ring motif. In the crystal, mol-ecules are linked by C-H⋯N and C-H⋯O hydrogen bonds, and consolidated into a three-dimensional architecture by π-π stacking inter-actions, with a centroid-centroid distance of 3.8428 (12) Å.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588362PMC
http://dx.doi.org/10.1107/S1600536812049859DOI Listing

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