In the crystal structure of the title compound, C11H15N3O2S, mol-ecules are linked by pairs of N-H⋯O and O-H⋯S hydrogen, forming inversion dimers. These dimers are linked by N-H⋯S hydrogen bonds, forming double-stranded chains propagating along the b-axis direction. The two C atoms of the end chain of the mol-ecule are disordered over two sets os sites [occupancy ratio 0.574 (9):0.426 (9)].

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588310PMC
http://dx.doi.org/10.1107/S1600536812049847DOI Listing

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In the crystal structure of the title compound, C11H15N3O2S, mol-ecules are linked by pairs of N-H⋯O and O-H⋯S hydrogen, forming inversion dimers. These dimers are linked by N-H⋯S hydrogen bonds, forming double-stranded chains propagating along the b-axis direction. The two C atoms of the end chain of the mol-ecule are disordered over two sets os sites [occupancy ratio 0.

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In the title compound, C11H15N3O2S·C2H3N, the dihedral angle between the benzene ring and the mean plane of the hydrazinecarbothio-amide group is 75.1 (2)°. In the crystal, the main mol-ecule is linked to the solvent mol-ecule by a weak N-H⋯N hydrogen bond while O-H⋯S hydrogen bonds link the mol-ecules into columns along [100].

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In the title compound, C(6)H(12)N(4)OS, an intra-molecular N-H⋯N hydrogen-bond is present giving rise to an S(5) ring motif. In the crystal, double-stranded chains propagating along [10[Formula: see text]] are formed via pairs of O-H⋯S and N-H⋯S hydrogen bonds. The chains are further stabilized by C-H⋯S interactions.

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