5-(Prop-2-yn-1-yl)-5H-dibenzo[b,f]azepine: ortho-rhom-bic polymorph.

Acta Crystallogr Sect E Struct Rep Online

Department of Physics, Faculty of Science, An Najah National University, Nabtus West Bank, Palestine.

Published: January 2013

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Article Abstract

In the title ortho-rhom-bic polymorph (space group Iba2), C17H13N, the dihedral angle between the benzene rings is 55.99 (10)° and the azepine ring adopts a boat conformation. In the crystal, mol-ecules are linked by C-H⋯π contacts. The previously-reported polymorph [Yousuf et al. (2012 ▶). Acta Cryst. E68, o1101] crystallizes in the monoclinic system (space group P21/c) with two mol-ecules in the asymmetric unit.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588308PMC
http://dx.doi.org/10.1107/S1600536812048908DOI Listing

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