In the title ortho-rhom-bic polymorph (space group Iba2), C17H13N, the dihedral angle between the benzene rings is 55.99 (10)° and the azepine ring adopts a boat conformation. In the crystal, mol-ecules are linked by C-H⋯π contacts. The previously-reported polymorph [Yousuf et al. (2012 ▶). Acta Cryst. E68, o1101] crystallizes in the monoclinic system (space group P21/c) with two mol-ecules in the asymmetric unit.
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http://dx.doi.org/10.1107/S1600536812048908 | DOI Listing |
IUCrdata
October 2024
Nelson Mandela University, Summerstrand Campus, Department of Chemistry, University Way, Summerstrand, PO Box 77000, Port Elizabeth, 6031, South Africa.
The title compound, CHO, is an α-hy-droxy-carb-oxy-lic acid whose ortho-rhom-bic polymorph has been reported earlier [Qiu (2007 ▸). , , 1819-1824]. The asymmetric unit contains two complete mol-ecules.
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February 2023
Institute of Physics, University of Neuchâtel, rue Emile-Argand 11, 2000 Neuchâtel, Switzerland.
The crystal structure of the title compound, CHBrN [systematic name: ()-,1-bis-(4-bromo-phen-yl)methanimine], is a second polymorph (Form II) crystallizing in the ortho-rhom-bic space group . The first polymorph (Form I) crystallizes in the monoclinic space group 2/ [Bernstein & Izak (1975 ▸). , 257-266; Marin (2013 ▸).
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January 2022
Purdue University, Department of Chemistry, 560 Oval Dr., West Lafayette, IN 47907, USA.
Substituted triazines are a class of compounds utilized for scavenging and sequestering hydrogen sulfide in oil and gas production operations. The reaction of one of these triazines under field conditions resulted in the formation of the title compound, 2-(1,3,5-di-thia-zinan-5-yl)ethanol, CHNOS, or MEA-di-thia-zine. Polymorphic form I, in space group 4/, was first reported in 2004 and its extended structure displays one-dimensional, helical strands connected through O-H⋯O hydrogen bonds.
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August 2021
M2i Salin, 36 Route Arles RD 36, 13129 Salin de Giraud, France.
Two polymorphs, () and (), of ()-{2-[(8,9,10,11,13,14,17)-11,17-dihy-droxy-10,13-dimethyl-3-oxo-2,6,7,8,9,11,12,14,15,16-deca-hydro-1-cyclo-penta-[]phenanthren-17-yl]-2-oxoeth-yl} 2,2-di-methyl-propane-thio-ate, CHOS, have been identified. They are ortho-rhom-bic, non-centrosymmetric (222). The structures display layers of mol-ecules conected O-H⋯O hydrogen bonds along the axis direction in polymorph () and along the axis direction in polymorph ().
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April 2021
Chemistry Division, Code 6189, Naval Research Laboratory, 4555 Overlook Av, SW, Washington DC 20375-5342, USA.
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