Dibromido(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N')(dimethyl sulfoxide-κO)cadmium.

Acta Crystallogr Sect E Struct Rep Online

Department of Chemistry, North Tehran Branch, Islamic Azad University, Tehran, Iran.

Published: January 2013

In the mol-ecule of the title compound, [CdBr2(C14H12N2)(C2H6OS)], the Cd(II) atom is five-coordinated in a distorted trigonal-bipyramidal configuration by two N atoms from a 2,9-dimethyl-1,10-phenanthroline ligand, one O atom from a dimethyl sulfoxide ligand and two Br atoms. In the crystal, π-π contacts between the pyridine and benzene rings [centroid-centroid distances = 3.710 (5), 3.711 (6) and 3.627 (5) Å] stabilize the structure.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588265PMC
http://dx.doi.org/10.1107/S1600536812050106DOI Listing

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