Dichlorido{N-[(5-methyl-thio-phen-2-yl)methyl-idene]-2-(pyridin-2-yl)ethanamine-κ(2) N,N'}palladium(II).

Acta Crystallogr Sect E Struct Rep Online

Chemistry Department, University of the Western Cape, Private Bag X17, Bellville 7535, South Africa.

Published: January 2013

In the title compound, [PdCl2(C13H14N2S)], the Pd(II) ion is coordinated by two N atoms of the chelating bidentate ligand and two chloride anions, giving rise to a distorted square-planar geometry. The methyl-substituted thio-phene arm and the pyridine ring are connected to the metal cation through N atoms to form a six-membered chelate ring with a boat conformation, making the complex stable.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588236PMC
http://dx.doi.org/10.1107/S1600536812049240DOI Listing

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