Methyl 2-(3-chloro-benzamido)-benzoate.

Acta Crystallogr Sect E Struct Rep Online

Laboratoire de Chimie Bio-organique et Macromoléculaire, Faculté des Sciences et Techniques Guéliz, Marrakech, Morocco.

Published: December 2012

In the mol-ecule of the title compound, C15H12ClNO3, the chloro-benzamide and benzoate units are almost co-planar, with a dihedral angle between the six-membered rings of 2.99 (10)°. An intra-molecular N-H⋯O hydrogen bond occurs. In the crystal, each mol-ecule is linked to a symmetry-equivalent counterpart across a twofold rotation axis by weak C-H⋯O and C-H⋯Cl hydrogen bonds, forming dimers. The packing is stabilized through weak π-π stacking along the b-axis direction, leading to π-stacked columns of inversion-related mol-ecules, with an inter-planar distance of 3.46 (2) Å and a centroid-centroid vector of 3.897 (2) Å.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588991PMC
http://dx.doi.org/10.1107/S1600536812046934DOI Listing

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Methyl 2-(3-chloro-benzamido)-benzoate.

Acta Crystallogr Sect E Struct Rep Online

December 2012

Laboratoire de Chimie Bio-organique et Macromoléculaire, Faculté des Sciences et Techniques Guéliz, Marrakech, Morocco.

In the mol-ecule of the title compound, C15H12ClNO3, the chloro-benzamide and benzoate units are almost co-planar, with a dihedral angle between the six-membered rings of 2.99 (10)°. An intra-molecular N-H⋯O hydrogen bond occurs.

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