CoO/Al-doped ZnO (AZO) multilayers exhibit ferromagnetism up to ~300 K. The magnetic behavior oscillates with odd vs even number of Co layers in the insulating antiferromagnetic CoO and (separately) with the thickness of the AZO layers and vanishes if AZO is replaced by intrinsic ZnO. Magnetization is due to uncompensated (111) ferromagnetic planes of insulating CoO for odd numbers of atomic planes per layer that are coupled together via RKKY exchange mediated by electron carriers in the nonmagnetic AZO layers. The period of the oscillation with AZO thickness qualitatively matches the Fermi wave vector calculated from the carrier concentration measured by ordinary Hall effect. Magnetic polarization of the AZO carriers is confirmed via an anomalous Hall effect that is proportional to the magnetization.
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http://dx.doi.org/10.1103/PhysRevLett.110.087206 | DOI Listing |
ACS Omega
January 2025
Department of Chemistry, Selcuk University, Konya 42130, Turkey.
The montmorillonite@iron oxide@silver (MMT@FeO@Ag) nanocomposite, which is recyclable and exhibits high catalytic activity, was evaluated for the degradation of methyl yellow (MY), a carcinogenic azo dye. For this purpose, MMT@FeO was first synthesized via the coprecipitation method and then Ag was doped to MMT@FeO via the chemical reduction method. MMT, MMT@FeO, and MMT@FeO@Ag were characterized by various techniques including scanning electron microscopy, Fourier transform infrared spectroscopy, X-ray diffraction, vibrating sample magnetometer, and thermal gravimetric analysis.
View Article and Find Full Text PDFSci Rep
January 2025
Faculty of Physics, Warsaw University of Technology, 75 Koszykowa Str., 00-662, Warszawa, Poland.
Surface relief grating formation in photo-responsive azo polymers under irradiation is a long-ago-found phenomenon, but all the factors governing its efficiency are still not fully recognized. Here, we report on the enormous impact of the polymer thickness on the possibility of fabrication of extremely high-amplitude surface deformations. We performed prolonged holographic recordings on the layers of the same azobenzene poly(ether imide), which had substantially different optical transmittances at the recording wavelength and revealed that the depths of the inscribed relief structures increased with the polymer thickness from a nondetectable value up to almost 2 µm, unaffected by the presence of a polymer-glass substrate interface in either sample.
View Article and Find Full Text PDFCureus
November 2024
Department of Applied Nutrition and Food Technology, Islamic University, Kushtia, BGD.
Chemosphere
December 2024
MAPS (Materials' Process - Structure correlations) Laboratory, Metallurgical and Materials Engineering, Indian Institute of Technology Patna, Bihta, Bihar, 801106, India. Electronic address:
Environmental remediation has emerged as a critical concern, with dye removal via adsorption being a particularly effective approach. This study demonstrates that appropriately synthesized Mg-Al-Layered Double Hydroxides (LDHs) exhibit exceptional adsorption capacities for anionic dyes. We investigate the impact of different washing media on the material's morphology, surface area, and adsorption capabilities.
View Article and Find Full Text PDFNanomaterials (Basel)
October 2024
Center for Hybrid Nanostructures (CHyN), University of Hamburg, Luruper Chaussee 149, 22761 Hamburg, Germany.
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