Unlabelled: As part of an ongoing study of soil vapor intrusion (SVI), concentration data for approximately 2000 air and vapor samples were assembled from remedial site investigations and stand-alone assessments conducted at New York State Manufactured Gas Plant (MGP) sites. Vapor samples were collected from ambient outdoor air indoor air, beneath building slabs, and from outside of buildings. Despite the large sample size, the considerable variability in compound and sample-specific censoring limits inhibited the use of conventional tools for statistical interpretation. This paper describes the development and application of improved statistical tools to address an unusually high degree of data censoring and possible artifacts related to uneven distributions of samples across sites and buildings. In addition to methods for calculating population percentiles and associated confidence intervals, methods for comparing the population of MGP-SVI data with a reference population were also developed and evaluated via illustrative comparisons with the published 2001 EPA Building Assessment Survey and Evaluation (BASE) study of industrial buildings. The focus of this work is on the development and evaluation of new statistical methods; a more complete summary and evaluation of the full NYS MGP-SVI data set will be presented in a companion paper.
Implications: Data from vapor intrusion and other environmental studies are often stratified and/or censored, which complicates comparisons with background data or reference populations. In some cases, statistical methods for censored data can be modified to support population-based inference and reduce biases associated with the presence of repeated measurements from multiple sources. Such modifications are particularly appropriate for retrospective data mining studies that are not guided by a formal experimental design.
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http://dx.doi.org/10.1080/10962247.2012.742473 | DOI Listing |
Ground Water Monit Remediat
June 2024
RTI International.
Subslab soil gas (SSSG) samples were collected as part of an investigation to evaluate vapor intrusion (VI) into a building. The June 2015 Office of Solid Waste and Emergency Response (OSWER) VI Guide (U.S.
View Article and Find Full Text PDFJ Hazard Mater
December 2024
School of Environment and Biological Engineering, Nanjing University of Science and Technology, Nanjing 210094, China; Norendar International LTD, Shijiazhuang 050000, China. Electronic address:
Water Res
December 2024
Equilon Enterprises LLC doing business as Shell Oil Products US, Houston, TX, USA.
This paper presents a simplified approach for the soil gas gradient method for estimating natural source zone depletion (NSZD) rates of specific contaminants of concern (COCs) at sites contaminated by light non-aqueous phase liquids (LNAPL). Traditional approaches to quantify COC-specific NSZD rates often rely on numerical or analytical reaction-transport models that require detailed site-specific data. In contrast, the proposed method employs simple analytical solutions, making it more accessible to practitioners.
View Article and Find Full Text PDFSmall
December 2024
College of Chemistry and Materials Science, Fujian Key Laboratory of Polymer Materials, Fujian Normal University, Fuzhou, 350117, China.
Void-free perovskite films with oriented large grains are considered good performance. However, contradictory requirements on solvent volatilization arise that the growth of large grains requires slow volatilization while the residual solvent problem, which leads to difficult-handled voids at buried interface, requires quick and complete volatilization. Currently, although grain boundary additives help reach large and oriented grains, the occupation of additives in the grain boundary volatilization channel may further deteriorate the residual solvent problem.
View Article and Find Full Text PDFInt J Pharm
October 2024
School of Pharmacy and Biomolecular Sciences, Liverpool John Moores University, Liverpool L3 3AF, United Kingdom. Electronic address:
Pulmonary drug delivery via aerosolization is a non-intrusive method for achieving localized and systemic effects. The aim of this study was to establish the impact of viscosity as a novel aspect (i.e.
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