Evaporative self-assembly of single-chain, polymeric nanoparticles.

Chem Commun (Camb)

Institute for Complex Molecular Systems, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven, The Netherlands.

Published: April 2013

Evaporative self-assembly of dilute solutions containing single-chain polymeric nanoparticles results in characteristic morphologies imaged using atomic force microscopy. Quantitative comparison of experimental data to morphologies obtained by lattice-gas simulations shows that the nonequilibrium patterns emerge from a complex interplay between dewetting, solvent evaporation and nanoparticle diffusion.

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Source
http://dx.doi.org/10.1039/c3cc40931gDOI Listing

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