Dimethyl-bis-(2-methyl-quinolin-8-olato-κ(2) N,O)tin(IV).

Acta Crystallogr Sect E Struct Rep Online

Department of Chemistry, General Campus, Shahid Beheshti University, Tehran 1983963113, Iran.

Published: December 2012

The Sn(IV) cation in the title compound, [Sn(CH3)2(C10H8NO)2], is N,O-chelated by two 2-methyl-quinolin-8-olate anions and coordinated by two methyl groups in a skew-trapezoidal bipyramidal geometry. In the mol-ecule, the two quinoline ring systems are twisted to one another at 10.91 (18)°. The dimethyl-tin skeleton [C-Sn-C = 149.6 (2)°] is bent over the longer edge of the trapezoid that is defined by the four chelating atoms. Weak inter-molecular C-H⋯O hydrogen bonding occurs in the crystal.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588791PMC
http://dx.doi.org/10.1107/S1600536812047393DOI Listing

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