Bromidotetra-kis-(2-ethyl-1H-imidazole-κN (3))copper(II) bromide.

Acta Crystallogr Sect E Struct Rep Online

Department of Inorganic Chemistry, Faculty of Chemistry, Gdansk University of Technology, 11/12 G. Narutowicz Street, 80233-PL Gdańsk, Poland.

Published: December 2012

The Cu(II) ion in the title mol-ecular salt, [CuBr(C5H8N2)4]Br, is coordinated in a square-pyramidal geometry by four N atoms of imidazole ligands and one bromide anion in the apical position. In the crystal, the ions are linked by N-H⋯Br hydrogen bonds involving both the coordinating and the free bromide species as acceptors. A C-H⋯Br inter-action is also observed. Overall, a three-dimensional network results.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588773PMC
http://dx.doi.org/10.1107/S1600536812047447DOI Listing

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