cis-Dichloridobis(2-isocyano-phenyl 4-meth-oxy-benzoate)palladium(II) chloro-form monosolvate.

Acta Crystallogr Sect E Struct Rep Online

Department of Chemistry, Saint-Petersburg State University, Universitetsky Pr. 26, 198504 Stary Petergof, Russian Federation.

Published: December 2012

In the title compound, [PdCl2(C15H11NO3)2]·CHCl3, the Pd(II) atom adopts a slightly distorted square-planar coordination geometry composed of two Cl atoms in cis positions and two C atoms from isocyano-phenyl ligands. The mol-ecular conformation is stabilized by π-π stacking inter-actions [shortest centroid-centroid distance = 3.600 (1) Å] between substituted benzene rings of different ligands. The crystal packing is characterized by C-H⋯O and C-H⋯Cl inter-actions involving the chloro-form solvent mol-ecules.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588737PMC
http://dx.doi.org/10.1107/S1600536812045801DOI Listing

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