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catena-Poly[[[aqua-(2,2'-bipyridine-κ(2) N,N')zinc]-μ-furan-2,5-dicarboxyl-ato-κ(2) O (2):O (5)] dihydrate]. | LitMetric

catena-Poly[[[aqua-(2,2'-bipyridine-κ(2) N,N')zinc]-μ-furan-2,5-dicarboxyl-ato-κ(2) O (2):O (5)] dihydrate].

Acta Crystallogr Sect E Struct Rep Online

School of Chemical Engineering, Changchun University of Technology, Changchun 130012, People's Republic of China.

Published: December 2012

In the title hydrated coordination polymer, {[Zn(C6H2O5)(C10H8N2)(H2O)]·2H2O} n , an infinite [1-10] chain is formed by the linking of [Zn(C10H8N2)(H2O)](2+) entities by bridging, monodentate furan-2,5-dicarboxyl-ate dianionic linkers. The Zn(2+) coordination geometry is a trigonal bipyramid, with one N atom (from 2,2'-bipyridine) and one O atom (from the bridging dianion) in the axial positions. For each Zn(II) atom, the dihedral angle between the furan ring of its coordinated bridging ligand and its coordinated bipyridine ring system is 87.19 (8)°. O-H⋯O hydrogen bonds involving both the coordinated and uncoordinated water mol-ecules generate a layer motif parallel to (001).

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588728PMC
http://dx.doi.org/10.1107/S1600536812045503DOI Listing

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