The Sn(IV) atom in the centrosymmetric title complex, [Sn2(CH3)4(NCS)2(OH)2], adopts a distorted trigonal-bipyramidal coordination environment defined by two methyl C atoms and one bridging hydroxide group in the equatorial plane while the other bridging hydroxide group and the N atom of the thio-cyanate anion are in the apical >positions. The dinuclear species are linked through O-H⋯S and C-H⋯ S hydrogen-bonding inter-actions into a three-dimensional network.
Download full-text PDF |
Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588706 | PMC |
| http://dx.doi.org/10.1107/S1600536812043462 | DOI Listing |
Publication Analysis
Top Keywords
bridging hydroxide
8
hydroxide group
8
di-μ-hydroxido-bis-[dimeth-ylthio-cyanato-κntiniv] sniv
4
sniv atom
4
atom centrosymmetric
4
centrosymmetric title
4
title complex
4
complex [sn2ch34ncs2oh2]
4
[sn2ch34ncs2oh2] adopts
4
adopts distorted
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!