The inhibitory kinetics of furfuryl alcohol, furfural and furoic acid on mushroom tyrosinase have been investigated. The results showed that these furan compounds were reversible inhibitors of the enzyme. Furthermore, furfuryl alcohol and furfural were found to be mixed-type inhibitors while furoic acid is uncompetitive inhibitor. The inhibition constants have been confirmed and the order of the inhibiting ability was furfural>furoic acid>furfuryl alcohol. They indicate that the functional groups on the furan ring play a crucial role in the inhibition on the enzyme. In addition, it was also found that these furan compounds could inhibit the proliferation of Salmonella bacteria and Bacillus subtilis to different extents. The minimum inhibitory concentration (MIC) values of furfuryl alcohol, furfural and furoic acid against B. subtilis and S. bacteria were 0.115, 0.027, 0.015 and 0.115, 0.029, 0.009 μM, respectively. The minimum bactericidal concentration (MBC) values of that were 0.115, 0.027, 0.015 and 0.231, 0.121, 0.030 μM, respectively.
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http://dx.doi.org/10.1016/j.ijbiomac.2013.02.019 | DOI Listing |
Chem Commun (Camb)
December 2024
Inorganic Materials & Heterogeneous Catalysis Laboratory, Department of Chemistry, School of Physical Sciences, Central University of Kerala, Tejaswini Hills Kasaragod, 671316 Kerala, India.
A tetragonal zirconia-faujasitic SAPO-37 zeolite composite (SAP-37ZR) was synergistically stabilised at 550 °C using a temperature programmed reduction method. The presence of the zeolite-ZrO composite phase was confirmed through powder XRD reflection, SEM and TEM-ED pattern analyses. The developed SAP-37ZR composite, exhibiting moderate acidity, was found to be highly active for the production of ethyl levulinate (EL) from furfuryl alcohol with a 99% yield.
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December 2024
Jiangxi Province Key Laboratory of Functional Crystalline Materials Chemistry, College of Chemistry and Chemical Engineering, Faculty of Materials Metallurgy and Chemistry, Jiangxi University of Science and Technology, Ganzhou 341000, Jiang Xi, China.
PdCu/NC and PdCo/NC with different metal mass ratios of Pd to Cu (or Co) are synthesized. They (Pd : Cu (or Co) = 3 : 7) show excellent catalytic activity and high selectivity to furfuryl alcohol (FA) (or tetrahydrofurfuryl alcohol (THFA)) under quite mild conditions due to synergistic effect of Pd-Cu (Co)-NC.
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November 2024
Department of Chemistry, School of Science, King Mongkut's Institute of Technology Ladkrabang Bangkok 10520 Thailand +66-2-324-8000.
Dalton Trans
December 2024
School of Chemistry and Chemical Engineering, Institute of Materials Sciences and Engineering, Institute of Clean Energy and Advanced Nanocatalysis (iClean), Anhui Province Key Laboratory of Coal Clean Conversion and High Valued Utilization, Anhui University of Technology, Maanshan 243002, China.
Utilizing photocatalytic technology for the value-added conversion of biomass derivatives, alongside the production of clean hydrogen energy, represents a viable approach to addressing energy and environmental challenges. However, the design of cost-effective and efficient photocatalysts remains a significant obstacle. In this work, we employed open-framework Prussian blue analogs as co-catalytic centers and combined them with ZnInS to construct a series of core-shell nanocube photocatalysts with varying metal compositions.
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November 2024
The Lab of Brewing Microbiology and Applied Enzymology, School of Biotechnology, Jiangnan University, Wuxi 214122, China.
The impact of mechanized processes on the properties of Xifeng Baijiu, as well as the differences between Baijiu produced through mechanized versus traditional methods, remains insufficiently understood. In this study, the differences in physicochemical properties, microorganisms, volatile flavor compounds, and their correlations in the traditional and mechanized processes of producing Xifeng Baijiu were compared. High-throughput sequencing revealed that the abundance and diversity of bacteria and fungi were higher in the traditional process compared to the mechanized one.
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