We experimentally determine the order of multiphoton induced luminescence of aluminum nanoantennas fabricated on a nonconductive substrate using electron-beam lithography to be 2.11 (±0.10). Furthermore, we optically characterize these nanostructures via linear dark-field microscopy and nonlinear multiphoton laser excitation. We hereby observe different spectral response functions that can be seen as a splitting of peak positions when the antenna arm length is increased to Larm > 150 nm which has not yet been reported for aluminum nanostructures.
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ACS Appl Mater Interfaces
August 2024
ICFO - Institut de Ciencies Fotoniques, The Barcelona Institute of Science and Technology, 08860 Castelldefels, Barcelona, Spain.
Nanophotonic biosensors offer exceptional sensitivity in the presence of strong background signals by enhancing and confining light in subwavelength volumes. In the field of nanophotonic biosensors, antenna-in-box (AiB) designs consisting of a nanoantenna within a nanoaperture have demonstrated remarkable single-molecule fluorescence detection sensitivities under physiologically relevant conditions. However, their full potential has not yet been exploited as current designs prohibit insightful correlative multicolor single-molecule studies and are limited in terms of throughput.
View Article and Find Full Text PDFProc Natl Acad Sci U S A
March 2024
Department of Chemistry, Rice University, Houston, TX 77005.
Aluminum nanocrystals (AlNCs) are of increasing interest as sustainable, earth-abundant nanoparticles for visible wavelength plasmonics and as versatile nanoantennas for energy-efficient plasmonic photocatalysis. Here, we show that annealing AlNCs under various gases and thermal conditions induces substantial, systematic changes in their surface oxide, modifying crystalline phase, surface morphology, density, and defect type and concentration. Tailoring the surface oxide properties enables AlNCs to function as all-aluminum-based antenna-reactor plasmonic photocatalysts, with the modified surface oxides providing varying reactivities and selectivities for several chemical reactions.
View Article and Find Full Text PDFACS Nano
November 2023
Aix Marseille Univ, CNRS, Centrale Marseille, Institut Fresnel, AMUTech, 13013 Marseille, France.
Plasmonic optical nanoantennas offer compelling solutions for enhancing light-matter interactions at the nanoscale. However, until now, their focus has been mainly limited to the visible and near-infrared regions, overlooking the immense potential of the ultraviolet (UV) range, where molecules exhibit their strongest absorption. Here, we present the realization of UV resonant nanogap antennas constructed from paired rhodium nanocubes.
View Article and Find Full Text PDFNanophotonics
June 2023
University of Montpellier, Institut d'Electronique et des Systèmes, Montpellier, Occitanie, France.
Surface-enhanced infrared absorption (SEIRA) spectroscopy is a competent method to detect trace quantity of molecules and even protein conformational flexibility by enhancing their vibrational modes. To improve the spectroscopy features, we propose a surface with honeycomb-like (HC) arrangement of aluminum equilateral triangles within a metal-insulator-metal configuration. With adjustable geometric parameters, the HC nanoantennas allow a tunable and wide spectral coverage in the IR.
View Article and Find Full Text PDFACS Nano
May 2023
ICFO-Institut de Ciencies Fotoniques, The Barcelona Institute of Science and Technology, 08860 Castelldefels (Barcelona), Spain.
Biosensing applications based on fluorescence detection often require single-molecule sensitivity in the presence of strong background signals. Plasmonic nanoantennas are particularly suitable for these tasks, as they can confine and enhance light in volumes far below the diffraction limit. The recently introduced antenna-in-box (AiB) platforms achieved high single-molecule detection sensitivity at high fluorophore concentrations by placing gold nanoantennas in a gold aperture.
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