Thiacloprid, a neonicotinoid insecticide with novel mode of action, is found to be effective against several lepidopteran as well as hemipteran pests. The present studies were carried out to observe the persistence pattern of thiacloprid on brinjal and to suggest suitable waiting period for the safety of consumers. Persistence of thiacloprid in brinjal was studied following three applications of thiacloprid (Alanto 240 SC) at 180 and 360 g a.i. ha(-1) at 7 days interval. Residues of thiacloprid in brinjal were estimated by high-performance liquid chromatography and were confirmed by liquid chromatography-mass spectrometry. The average initial deposits of thiacloprid were observed to be 0.48 and 1.05 mg kg(-1) on the brinjal fruit following third application of thiacloprid at recommended and double the recommended dosages, respectively. Half-life periods for thiacloprid were found to be 0.47 and 0.50 days at single and double the application rates, respectively. Residues of thiacloprid declined below its limit of quantification of 0.05 mg kg(-1) after 3 and 5 days, respectively, at recommended and double the recommended application rates. Therefore, the use of thiacloprid does not seem to pose any risk hazard and a waiting period of 1 day is suggested for safe consumption of brinjal fruits.
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http://dx.doi.org/10.1007/s10661-013-3145-z | DOI Listing |
J AOAC Int
May 2017
Anand Agricultural University, All India Network Project on Pesticide Residues, Pesticide Residue Laboratory, Anand, Gujarat, India 388 110.
The study was conducted to investigate matrix interferences using QuEChERS sample preparation to understand whether the dilution of matrix and/or the grouping of commodities can eliminate the need for selective individual matrix-matched standards in LC with tandem MS (MS/MS) analysis, and whether the calibration graph based on only one matrix can be used for quantification in the other matrixes. Matrix effects (MEs) were studied by comparing the slopes of calibration curves of the matrix-matched standards (diluted with mobile phase) vis-à-vis the solvent-based standards. The present study showed that MEs were dependent on the nature of both the commodity and the analyte.
View Article and Find Full Text PDFEnviron Monit Assess
September 2013
Pesticide Residue Analysis Laboratory, Department of Entomology, Punjab Agricultural University, Ludhiana, 141004 Punjab, India.
Thiacloprid, a neonicotinoid insecticide with novel mode of action, is found to be effective against several lepidopteran as well as hemipteran pests. The present studies were carried out to observe the persistence pattern of thiacloprid on brinjal and to suggest suitable waiting period for the safety of consumers. Persistence of thiacloprid in brinjal was studied following three applications of thiacloprid (Alanto 240 SC) at 180 and 360 g a.
View Article and Find Full Text PDFPest Manag Sci
February 2009
Division of Agricultural Chemicals, Indian Agricultural Research Institute, New Delhi 110012, India.
Background: Thiacloprid [(Z)-3-(6-chloro-3-pyridylmethyl)-1,3-thiazolidin-2-ylidenecyanamide; Calypso] is a systemic insecticide having persistence in the plant system. It was chosen for the management of the eggplant shoot and fruit borer, Leucinodes orbonalis Guen. Management of this insect pest is difficult because it harbours inside the shoot and fruit portions of eggplant.
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