A new NiO-based material Pb2Ni(PO4)2 was obtained by a conventional solid-state reaction in air. The crystal structure exhibits both corner- and edge-sharing {Ni-O-P} bonds in the system. Magnetic properties were investigated by means of magnetic susceptibility, magnetization, and heat capacity measurements. The results show a typical three-dimensional antiferromagnetic ordering below ~4 K and a field-induced spin-flop transition below the Néel temperature.
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| http://dx.doi.org/10.1039/c3dt00030c | DOI Listing |
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