A second monoclinic polymorph of (E)-phen-yl(pyridin-2-yl)methanone oxime.

Acta Crystallogr Sect E Struct Rep Online

Instituto de Química, Universidad Nacional Autónoma de México, Circuito exterior, Ciudad Universitaria, México, DF, 04510, Mexico.

Published: February 2013

The title compound, C(12)H(10)N(2)O, a second monoclinic poly-morph of (E)-phen-yl(pyridin-2-yl)methanone oxime crystallizes in the space group P2(1)/n (Z = 4). The previously reported polymorph [Taga et al. (1990 ▶). Acta Cryst. C46, 2241-2243] occurs in the space group C2/c (Z = 8). In the crystal, pairs of bifurcated O-H⋯(N,O) hydrogen bonds link the mol-ecules into inversion dimers. The dimers are linked by C-H⋯π inter-actions, forming a linear arrangement. The dihedral angle between the pyridine and phenyl rings is 67.70 (8)°.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569829PMC
http://dx.doi.org/10.1107/S1600536813002377DOI Listing

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