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Acetonyltriphenyl-phospho-nium nitrate. | LitMetric

Acetonyltriphenyl-phospho-nium nitrate.

Acta Crystallogr Sect E Struct Rep Online

Laboratoire de Chimie Minerale et Analytique, Departement de Chimie, Faculté des Sciences et Techniques, Université Cheikh Anta Diop, Dakar, Senegal.

Published: February 2013

Crystals of the title salt, C(21)H(20)OP(+)·NO(3) (-), are composed of acetonyltriphenyl-phospho-nium cations and nitrate anions that mainly inter-act through electrostatic forces. The P atom in the cation has a slightly distorted tetra-hedral environment, with C-P-C angles ranging from 104.79 (7) to 112.59 (6)°. The sum of O-N-O angles of the nitrate anion is 359.99°, reflecting its trigonal-planar character. C-H⋯O hydrogen bonds help to consolidate the crystal packing.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569822PMC
http://dx.doi.org/10.1107/S1600536813002110DOI Listing

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