2-Chloro-N-methyl-N-[2-(methyl-amino)-phen-yl]acetamide.

Acta Crystallogr Sect E Struct Rep Online

College of Science, Northwest A&F University, Yangling Shaanxi 712100, People's Republic of China.

Published: February 2013

The title compound, C(10)H(13)ClN(2)O, was obtained as a by-product in the reaction of 2-chloro-methyl-1H-benzimidazole, dimethyl sulfate and toluene to synthesise 2-chloro-methyl-1-methyl-benzimidazole. The dihedral angle between the benzene ring and the acetamide group is 89.72  (6)° while that between the aromatic ring and the chloracetyl group is 84.40 (4)°. In the crystal, adjacent mol-ecules are linked by pairs of N-H⋯O hydrogen bonds into inversion dimers.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569763PMC
http://dx.doi.org/10.1107/S1600536813000494DOI Listing

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