Weighting of topologically different interactions in a model of two-dimensional polymer collapse.

Phys Rev E Stat Nonlin Soft Matter Phys

Department of Mathematics and Statistics, The University of Melbourne, 3010, Australia.

Published: January 2013

We study by computer simulation a recently introduced generalized model of self-interacting self-avoiding trails on the square lattice that distinguishes two topologically different types of self-interaction: namely, crossings where the trail passes across itself and collisions where the lattice path visits the same site without crossing. This model generalizes the canonical interacting self-avoiding trail model of polymer collapse, which has a strongly divergent specific heat at its transition point. We confirm the recent prediction that the asymmetry does not affect the universality class for a range of asymmetry. Certainly, where the weighting of collisions outweighs that of crossings this is well supported numerically. When crossings are weighted heavily relative to collisions, the collapse transition reverts to the canonical θ-point-like behavior found in interacting self-avoiding walks.

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http://dx.doi.org/10.1103/PhysRevE.87.012142DOI Listing

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