The reaction between HTcO(4) and MeOH in 13 M H(2)SO(4) was investigated by (99)Tc NMR, UV-visible and X-ray absorption fine structure (XAFS) spectroscopy. Experimental results and first principles calculations show the formation of Tc(+5) sulfate complexes. The results expand the fundamental understanding of Tc in high acid solutions.
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| http://dx.doi.org/10.1039/c3dt32951h | DOI Listing |
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