Convenient preparative routes to mononuclear ruthenium complexes containing the 2,4-pentadiynylnitrile, or cyanobutadiynyl, ligand are described. The electronic properties of the [C(5)N](-) ligand are closely related to those of not only the cyanide ([CN](-)) and 2-propynylnitrile or cyanoacetylide ([C≡CC≡N](-)) ligands, but also those of the isoelectronic polyynyl ([{C≡C}(n)R](-)) ligands.
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| http://dx.doi.org/10.1039/c3dt33052d | DOI Listing |
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