Catalytic enantioselective 1,2-diboration of 1,3-dienes followed by cascade allylborations with dicarbonyls provides rapid entry into carbocyclic reaction products. The stereochemical course of this reaction was studied along with its application in the synthesis of pumilaside aglycon.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3625973 | PMC |
| http://dx.doi.org/10.1021/ja400506j | DOI Listing |
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