Bimetallic Janus nanostructures via programmed shell growth.

Nanoscale

Department of Mechanical Engineering and Materials Science, Washington University in St. Louis, 1 Brooking Dr, St. Louis, MO 63130, USA.

Published: March 2013

AI Article Synopsis

  • The study focuses on creating asymmetric core-Janus shell plasmonic nanostructures using gold (Au) and silver (Ag) nanoparticles, highlighting the innovative synthesis methods employed.
  • Kinetic control was crucial for ensuring the asymmetric growth of the shell on Au cores, leading to unique nanostructures with tailored optical properties.
  • These nanostructures exhibit strong Raman activity, making them promising for applications in biosensing and bioimaging, potentially enhancing analytical techniques in biological research.

Article Abstract

We report the synthesis of compositionally asymmetric, core-Janus shell plasmonic nanostructures comprised of Au and Ag. Kinetic control was employed to achieve asymmetric shell growth on Au nanoparticles acting as cores. Subsequent differential surface functionalization of these nanostructures enabled programmed shell growth resulting in core-Janus shell nanostructures. UV/vis extinction spectra reveal that the localized surface plasmon resonance of the nanostructures depends on the composition and distribution of the components, providing additional handles to tune the optical properties of metal nanostructures. The core-Janus shell nanostructures demonstrated here are highly Raman-active making them attractive candidates for Raman-based biosensing and bioimaging applications.

Download full-text PDF

Source
http://dx.doi.org/10.1039/c3nr34321aDOI Listing

Publication Analysis

Top Keywords

shell growth
12
core-janus shell
12
programmed shell
8
shell nanostructures
8
nanostructures
7
shell
6
bimetallic janus
4
janus nanostructures
4
nanostructures programmed
4
growth report
4

Similar Publications

Piezoelectric catalysis possesses the potential to convert ocean wave energy into and holds broad prospects for extracting uranium from seawater. Herein, the Z-type ZnO@COF heterostructure composite with excellent piezoelectric properties was synthesized through in situ growth of covalent organic frameworks (COFs) on the surface of ZnO and used for efficient uranium extraction. The designed COFs shell enables ZnO with stability, abundant active sites and high-speed electron transport channels.

View Article and Find Full Text PDF

Tailored large-particle quantum dots with high color purity and excellent electroluminescent efficiency.

Sci Bull (Beijing)

January 2025

Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices, Institute of Functional Nano & Soft Materials (FUNSOM), Soochow University, Suzhou 215123, China; Macao Institute of Materials Science and Engineering (MIMSE), MUST-SUDA Joint Research Center for Advanced Functional Materials, Zhuhai MUST Science and Technology Research Institute, Macau University of Science and Technology, Macao 999078, China; Institute of Organic Optoelectronics (IOO), Jiangsu Industrial Technology Research Institute (JITRI), Suzhou 215200, China. Electronic address:

High-quality quantum dots (QDs) possess superior electroluminescent efficiencies and ultra-narrow emission linewidths are essential for realizing ultra-high definition QD light-emitting diodes (QLEDs). However, the synthesis of such QDs remains challenging. In this study, we present a facile high-temperature successive ion layer adsorption and reaction (HT-SILAR) strategy for the growth of precisely tailored ZnCdSe/ZnSe shells, and the consequent production of high-quality, large-particle, alloyed red CdZnSe/ZnCdSe/ZnSe/ZnS/CdZnS QDs.

View Article and Find Full Text PDF

Mechanistic Insights into CO Adsorption of LiSiO at High Temperature.

Materials (Basel)

January 2025

Hunan Key Laboratory of Applied Environmental Photocatalysis, School of Materials and Environmental Engineering, Changsha University, Changsha 410022, China.

The development of materials with high adsorption capacity for capturing CO from industrial exhaust gases has proceeded rapidly in recent years. LiSiO has attracted attention due to its low cost, high capture capacity, and good cycling stability for direct high-temperature CO capture. Thus far, the CO adsorption mechanism of LiSiO is poorly understood, and detailed phase transformations during the CO adsorption process are missing.

View Article and Find Full Text PDF

Dietary Tannic Acid Promotes Growth Performance and Resistance Against Infection by Improving the Antioxidative Capacity and Intestinal Health in the Chinese Soft-Shelled Turtle ().

Antioxidants (Basel)

January 2025

Key Laboratory of Tropical and Subtropical Fishery Resources Application and Cultivation, Ministry of Agriculture and Rural Affairs, Pearl River Fisheries Research Institute, Chinese Academy of Fishery Sciences, Guangzhou 510380, China.

To investigate the effect of tannic acid (TA) on the growth, disease resistance, and intestinal health of Chinese soft-shelled turtles, individual turtles were fed with 0 g/kg (CG), 0.5 g/kg, 1 g/kg, 2 g/kg, and 4 g/kg TA diets for 98 days. Afterwards, the turtles' disease resistance was tested using .

View Article and Find Full Text PDF

Impact of fresh-cut onion types and flavonoid profiles on the survival kinetics of foodborne pathogen during refrigerated storage.

Int J Food Microbiol

January 2025

School of Earth, Environmental, and Marine Sciences, University of Texas Rio Grande Valley, 1201 W University Dr, Edinburg, TX 78539, USA.

This study investigated the effect of onion flavonoid profiles on the growth, survival, and/or death kinetics of foodborne pathogens in fresh-cut onions at 4 °C. Fresh-cut white, yellow, red, and sweet onions were inoculated with separate four-strain cocktail(s) of nalidixic acid-adapted Salmonella spp., Escherichia coli O157:H7, and Listeria monocytogenes achieving a 4 to 5 log CFU g.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!