We investigated mass and charge transport in amorphous salt-in-poly(ethylene oxide) (PEO) electrolytes with NaI and/or the ionic liquid (IL) EMImTFSI (1-ethyl-3-methylimizadolium bis(trifluoromethylsulfonyl)imide) as salt component. Combining the results of ion conductivity, pulsed field gradient nuclear magnetic resonance, and radiotracer diffusion measurements, it is found that over wide temperature ranges both the cation and anion diffusion coefficients and the charge diffusivity are distinctly larger in PEO(20)EMImTFSI than in PEO(20)NaI complexes, where the monomer-to-salt mole ratio equals 20. In the mixed-salt complexes PEO(20)NaI(1)EMImTFSI(1) and PEO(20)NaI(0.5)EMImTFSI(0.5), we observe a slowing down of the IL ions EMIm and TFSI along with a diffusivity enhancement of the I anion compared to the single-salt base complexes. For the cation Na, a diffusivity increase is only effected by IL substitution, but because of the concomitant decrease of the Na concentration, it does not predict more effective charge transfer in a battery cell configuration.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1021/jp311563h | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Anticorrosion properties of ionic liquid functionalized graphene oxide epoxy composite coating on the carbon steel for CCUS environment.
Environ Sci Pollut Res Int
January 2025
Department of Chemical Engineering, Indian Institute of Technology Guwahati, Guwahati, 781039, Assam, India.
The adoption of carbon capture, utilization, and storage (CCUS) technology is increasingly prevalent, driven by the global initiative to conserve energy and reduce emissions. Nevertheless, CCUS has the potential to induce corrosion in equipment, particularly in high-pressure environments containing carbon dioxide (CO). Therefore, anti-corrosion protection is necessary for the metal utilized for CO production and storage equipment.
View Article and Find Full Text PDFOn the formation and stability mechanisms of diverse lipid-based nanostructures for drug delivery.
Adv Colloid Interface Sci
January 2025
Department of Chemistry and Biotechnology, School of Science, Computing and Engineering Technologies, Swinburne University of Technology, Melbourne, Australia.
In the evolving landscape of nanotechnology and pharmaceuticals, lipid nanostructures have emerged as pivotal areas of research due to their unique ability to mimic biological membranes and encapsulate active molecules. These nanostructures offer promising avenues for drug delivery, vaccine development, and diagnostic applications. This comprehensive review explores the complex mechanisms underlying the formation and stability of various lipid nanostructures, including lipid liquid crystalline nanoparticles and solid lipid nanoparticles.
View Article and Find Full Text PDFStructural transitions of ionic microgel solutions driven by circularly polarized electric fields.
Soft Matter
January 2025
Faculty of Physics, University of Vienna, Boltzmanngasse 5, 1090 Vienna, Austria.
In this work, a theoretical approach is developed to investigate the structural properties of ionic microgels induced by a circularly polarized (CP) electric field. Following a similar study on chain formation in the presence of linearly polarized fields [T. Colla , , 2018, , 4321-4337], we propose an effective potential between microgels which incorporates the field-induced interactions a static, time averaged polarizing charge at the particle surface.
View Article and Find Full Text PDFExploring the Conformational Space of a Sulfonyl-Based Ionic Liquid on Platinum-Based Mono and Bimetallic Surfaces.
Langmuir
January 2025
Centre for Computational and Data Sciences, Indian Institute of Technology Kharagpur, West Bengal 721302, India.
Understanding the arrangement of ionic liquids at the interface and their interactions with the surface is crucial for enhancing selectivity in heterogeneous reactions for practical applications. In this study, we investigate the nature of the adsorption and structural orientations of a sulfonyl-based ionic liquid on platinum-based mono- and bimetallic (111) surfaces employing replica exchange molecular dynamics and first-principles density functional theory calculations. More than 30 confirmations of the ionic liquid are identified on both monometallic and bimetallic surfaces.
View Article and Find Full Text PDFCorrection: Structure, dynamic, and free energy analyses of 5-hydroxymethylfurfural in aprotic solvents and imidazolium ionic liquids using all-atom molecular dynamics simulations.
Phys Chem Chem Phys
January 2025
Department of Chemical Engineering, Indian Institute of Technology Jodhpur, Jodhpur-342037, India.
Correction for 'Structure, dynamic, and free energy analyses of 5-hydroxymethylfurfural in aprotic solvents and imidazolium ionic liquids using all-atom molecular dynamics simulations' by Sweta Jha , , 2024, , 28417-28430, https://doi.org/10.1039/D4CP02914C.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!