A facile, flexible and large-scale technique was proposed to prepare a CuO-CNT 3D-network composite with the aid of electrostatic interactions in aqueous solution. The composite greatly improves the electrochemical performance. At a rate of 0.1 C, the cycling discharge capacity of the optimal composite is more than 2.3 times of that of unmodified mesoporous CuO nanosheets as the active material in an anode after 40 cycles.
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http://dx.doi.org/10.1039/c3nr34070h | DOI Listing |
Mikrochim Acta
January 2025
Electroanalytical Chemistry Research Laboratory, Department of Analytical Chemistry, Faculty of Chemistry, University of Mazandaran, Babolsar, Iran.
A novel electrochemical aptasensor based on bimetallic zirconium and copper oxides embedded within mesoporous carbon (denoted as ZrOCuO@mC) was constructed to detect miRNA. The porous ZrOCuO@mC was created through the pyrolysis of bimetallic zirconium/copper-based metal-organic framework (ZrCu-MOF). The substantial surface area and high porosity of ZrOCuO@mC nanocomposite along with its robust affinity toward aptamer strands, facilitated the effective anchoring of aptamer strands on the ZrOCuO@mC-modified electrode surface.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
Bioengineering Division, Hacettepe University, Ankara 06800, Turkey.
Uniform, mesoporous copper(II) oxide nanospindles (CuO NSs) were synthesized via a method based on templated hydrothermal oxidation of copper in the presence of monodisperse poly(glycerol dimethacrylate--methacrylic acid) nanoparticles (poly(GDMA--MAA) NPs). Subsequent decoration of CuO NSs with a CaO nanoshell (CuO@CaO NSs) yielded a nanozyme capable of Cu(I)/Cu(II) redox cycling. Activation of the Cu(I)/Cu(II) cycle by exogenously generated HO from the CaO nanoshell significantly enhanced glutathione (GSH) depletion.
View Article and Find Full Text PDFJ Trace Elem Med Biol
November 2024
Institute of Biomaterials, University of Erlangen-Nuremberg, Erlangen 91058, Germany. Electronic address:
Introduction: The incorporation of trace elements such as strontium (Sr) and copper (Cu) in the composition of mesoporous bioactive glass (MBG) is widely known to enhance its biological functionality for bone tissue regeneration METHODS: Two MBG powders with the composition 80SiO-11CaO-5PO-xCuO/SrO, one doped with 4 mol.% of CuO, the second with 4 mol.% of SrO were blended in the weight ratios of Cu-MBG: Sr-MBG; 100:0, 70: 30, 50: 50, 30: 70 and 0:100 aiming at minimizing Cu to minimize the cytotoxicity of Cu while preserving its antimicrobial activity.
View Article and Find Full Text PDFACS Appl Mater Interfaces
November 2024
Department of Urology, Second Affiliated Hospital of Xi'an Jiaotong University, Xi'an 710004, Shaanxi China.
As antibiotic resistance increases, alternative antimicrobial methods become essential. Chemical dynamics therapy (CDT) utilizing copper peroxide (CuO) nanodots shows significant potential in antibacterial applications due to its ability to self-supply hydrogen peroxide (HO) on its own. This characteristic effectively addresses the challenges of low HO levels and high glutathione (GSH) expression in the bacterial infection microenvironment.
View Article and Find Full Text PDFInorg Chem
November 2024
Department of Chemistry, Bilkent University, 06800 Ankara, Turkey.
Stable porous manganese oxide-based electrodes are essential for clean energy generation and storage because of their high natural abundance and health safety. This investigation focuses on mesoporous LiMnMO (where M is Fe, Co, Ni, and Cu and is 0, 0.1, 0.
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