Organosiloxane supramolecular liquids--surface-energy-driven phase transitions.

Angew Chem Int Ed Engl

School of Engineering Technology, Eastern Michigan University, Ypsilanti, MI 48197, USA.

Published: February 2013

Autocondensation of organoalkoxysilanes and subsequent anion exchange produces organosiloxane supramolecular liquids which are core-free and solvent-free nanoparticle nanofluids. This hybrid supramolecular liquid, [C(81)H(156)NO(3)S(SiO([2>x>3/2]))](y), exhibits (see TEM image; 200 nm width) interparticle menisci and softness (from imputed deformations) of interparticle potential.

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http://dx.doi.org/10.1002/anie.201208725DOI Listing

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