Multicomponent Fe(II)-iminopyridine-based self-assemblies have been synthesized with variably sized internal functionality. Larger internal functions provide increased strain to the complex and confer diastereocontrol upon the assembly process. Complete diastereocontrol is possible upon the introduction of large achiral groups on the cavity interior.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1039/c3cc37912d | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Endohedral isomerism in model achiral and chiral La@CN systems.
Spectrochim Acta A Mol Biomol Spectrosc
April 2020
Institute of Nuclear Chemistry and Technology, 16 Dorodna-Street, 03-195 Warsaw, Poland. Electronic address:
Endohedral structures with La or La encapsulated in chiral (1,16)CN or achiral (1,4)CN diazafullerenes were studied at the B3LYP/G-31G*/SDD level. Two stable locations of La and La are possible in each cage but only with La@(1,16)CN can the two isomers coexist. We found that an AIM determined hapticity of the endohedral species selectively differentiates the systems.
View Article and Find Full Text PDFAchiral endohedral functionality provides stereochemical control in Fe(II)-based self-assemblies.
Chem Commun (Camb)
February 2013
Department of Chemistry, University of California - Riverside, Riverside, California 92521, USA.
Multicomponent Fe(II)-iminopyridine-based self-assemblies have been synthesized with variably sized internal functionality. Larger internal functions provide increased strain to the complex and confer diastereocontrol upon the assembly process. Complete diastereocontrol is possible upon the introduction of large achiral groups on the cavity interior.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!