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A polar tetrazolyl-carboxyl microporous Zn(II)-MOF: sorption and luminescent properties. | LitMetric

A polar tetrazolyl-carboxyl microporous Zn(II)-MOF: sorption and luminescent properties.

Dalton Trans

Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry and Materials Science, Northwest University, Xi'an 710069, P.R. China.

Published: March 2013

AI Article Synopsis

Article Abstract

A Zn(II)-MOF [Zn(2)(tzba)(DMF)]·0.5DMF (1) (H(2)tzba = 4-(1H-tetrazol-5-yl) benzoic acid, DMF = N,N'-dimethylformamide) has been solvothermally synthesized and characterized. 1 is a three-dimensional (3D) microporous framework possessing an unusual multi-nodal (3,3,6)- or (4,4,4,4)-connected topological net. The small-sized pores, open metal sites, phenyl π systems and tetrazolyl groups of tzba(2-) decorating the pore with high polarity enable 1 to attract strongly for CO(2), which leads to high sorption heat for CO(2) and significant selectivities for CO(2) over H(2) and N(2). In addition, 1 and desolvated 1' display strong and weak blue luminescence in solid state, respectively, being mainly related to the framework vibration due to the residing and releasing of DMF molecules in the channel.

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Source
http://dx.doi.org/10.1039/c2dt31968cDOI Listing

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