A model for tribofilm growth is developed. The model is used in combination with numerical contact mechanics tools to enable evaluation of the combined effects of chemistry and contact mechanics. The model is tuned with experimental data and is thereafter applied to rough surfaces. The growth of the tribofilm is evaluated for 3 different contact cases and short-term tribofilm growth behaviour is analyzed. The results show how tribofilms grow in patches. The model is expected to be used as a tool for analysis of the interaction between rough surfaces.
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http://dx.doi.org/10.1039/c2fd00132b | DOI Listing |
J Phys Chem C Nanomater Interfaces
September 2024
Department of Mechanical Engineering, Imperial College London, London SW7 2AZ, U.K.
Phosphate esters decompose on metal surfaces and form protective polyphosphate films. For many applications, such as in lubricants for electric vehicles and wind turbines, an understanding of the effect of electric fields on molecular decomposition is urgently required. Experimental investigations have yielded contradictory results, with some suggesting that electric fields improve tribological performance, while others have reported the opposite effect.
View Article and Find Full Text PDFLangmuir
February 2024
Department of Materials Science and Engineering, Indian Institute of Technology Delhi, Hauz Khas, New Delhi 110016, India.
Zinc dialkyl dithiophosphate (ZDDP) is a key antiwear additive in lubricants that forms robust phosphate glass-based tribofilms to mitigate wear on rubbing surfaces. The quest to unravel the enigma of these antiwear film formations on sliding surfaces has persisted as an enduring mystery, despite nearly a century of fervent research. This paper presents a comprehensive review of nanotribological investigations, centering on the tribochemical decomposition of ZDDP antiwear additives.
View Article and Find Full Text PDFPhys Chem Chem Phys
December 2023
Department of Mechanical Engineering, Imperial College London, South Kensington Campus, SW7 2AZ, London, UK.
The growth of protective tribofilms from lubricant antiwear additives on rubbing surfaces is initiated by mechanochemically promoted dissociation reactions. These processes are not well understood at the molecular scale for many important additives, such as tricresyl phosphate (TCP). One aspect that needs further clarification is the extent to which the surface properties affect the mechanochemical decomposition.
View Article and Find Full Text PDFNanomicro Lett
October 2023
State Key Laboratory of Powder Metallurgy, Central South University, Changsha, 410083, People's Republic of China.
The practical application of Li metal anodes (LMAs) is limited by uncontrolled dendrite growth and side reactions. Herein, we propose a new friction-induced strategy to produce high-performance thin Li anode (Li@CFO). By virtue of the in situ friction reaction between fluoropolymer grease and Li strips during rolling, a robust organic/inorganic hybrid interlayer (lithiophilic LiF/LiC framework hybridized -CF-O-CF- chains) was formed atop Li metal.
View Article and Find Full Text PDFFaraday Discuss
January 2023
Department of Mechanical Engineering & Applied Mechanics, University of Pennsylvania, Philadelphia, Pennsylvania 19104, USA.
Zinc dialkyldithiophosphate (ZDDP), the most widely used antiwear additive in engine oils, has been extensively studied over the last few decades to help understand the origin of its effectiveness. Glassy phosphate-based tribofilms, approximately 100 nm thick, are often formed on surfaces sliding in ZDDP-containing oils, which help to prevent or reduce wear. Recent studies reveal that a combination of applied shear and compressive stresses drive mechanochemical reactions that promote tribofilm growth, and that growth is further accelerated by increased temperature.
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