The title mol-ecule, C(23)H(26)N(2)O(8), was synthesized in three steps starting from m-nitro-cinnamic acid. The central oxazolidine ring adopts an almost perfect envelope conformation with the O atom as the flap [puckering parameter ϕ = 0.3 (6)°]. The dihedral angle formed by the benzene rings is 61.81 (9)°. In the crystal, mol-ecules are connected into double chains parallel to [010] by C-H⋯O hydrogen bonds. The absolute configuration was assigned from the synthetic procedure.
Download full-text PDF |
Source |
---|---|
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515246 | PMC |
http://dx.doi.org/10.1107/S160053681204192X | DOI Listing |
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!