catena-Poly[[[aqua-(2,2'-bipyridine-κ(2)N,N')copper(II)]-μ-furan-2,5-di-carboxyl-ato-κ(2)O(2):O(5)] dihydrate].

Acta Crystallogr Sect E Struct Rep Online

School of Chemical Engineering, Changchun University of Technology, Changchun 130012, People's Republic of China.

Published: November 2012

In the crystal structure of the title compound, {[Cu(C(6)H(2)O(5))(C(10)H(8)N(2))(H(2)O)]·2H(2)O}(n), an infinite chain parallel to [110] is formed by the linking of Cu(H(2)O)(2,2'-bipyridine) units through a furan-2,5-dicarboxyl-ate bridge. The Cu(II) atom shows a square-pyramidal geometry, with one furan-2,5-dicarboxyl-ate O atom in the apical position. The dihedral angle between the planes of the furan ring and the bipyridine mol-ecule is 83.88 (7)°. O(water)-H⋯O hydrogen bonds connect adjacent chains, generating a layer motif parallel to (001).

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515153PMC
http://dx.doi.org/10.1107/S1600536812043632DOI Listing

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