trans-Dichloridobis(4-nitro-aniline-κN(1))palladium(II).

Acta Crystallogr Sect E Struct Rep Online

College of Mathematics, Physics and Software Engineering, Lanzhou Jiaotong University, Lanzhou 730070, People's Republic of China.

Published: November 2012

In the title compound, [PdCl(2)(C(6)H(6)N(2)O(2))(2)], the Pd(II) atom is coordinated in a distorted square-planar geometry by two N atoms from two 4-nitro-aniline ligands and two Cl atoms in a trans arrangement. Inter-molecular N-H⋯Cl hydrogen bonds involving the amino groups and chloride anions lead to a chain along [100]. These chains are further self-assembled into a three-dimensional network through N-H⋯O and N-H⋯Cl hydrogen bonds.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515110PMC
http://dx.doi.org/10.1107/S1600536812042134DOI Listing

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