Detecting bifurcations in an electrochemical cell employing an assisted reference model strategy.

J Phys Chem A

Departamento de Ingeniería Química, Instituto Tecnológico de Celaya, Av. Tecnológico y A. García Cubas s/n, 38010 Celaya, Guanajuato, México.

Published: January 2013

Bifurcations are detected in experiments involving the electrochemical oxidation of copper in phosphoric acid. Ideally, a bifurcation detection protocol requires a model with good qualitative and quantitative prediction capabilities that is also able to reproduce the drift inherent to the electrochemical experiment. A generic protocol for manipulation of nonlinear systems is proposed to achieve this goal. This protocol is based on a good qualitative predictor coupled to a modified Kalman filter that corrects the quantitative errors of the model point by point, adapting to the slowly varying conditions imposed by the electrochemical drift.

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http://dx.doi.org/10.1021/jp310127aDOI Listing

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