A Mueller-Stokes analysis is applied to pure bismuth thin film samples prepared by the laser ablation technique by using a polarimeter with a 632.8 nm continuum wavelength laser. The complex refractive index is determined in the range of 250-1100 nm. Results from the Mueller matrix show the high sensitivity of diattenuation and polarizance parameters as a function of the sample thickness and the incidence angle, except at the pseudo-Brewster angle, where they exhibit the same value. Results show that the knowledge of the polarimetric response, with appropriate incident polarization states, could be used to design photonic Bi-based devices for several applications. Polarization dependence is the result of changes on the surface morphology as a result of the small value of the skin depth.
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http://dx.doi.org/10.1364/AO.51.008549 | DOI Listing |
J Fluoresc
January 2025
Department of Physics, Acharya Nagarjuna University, Nagarjuna Nagar, Andhra Pradesh, 522510, India.
In this work, the conventional melt quenching approach is used to synthesize the Pr doped NaF-BiO-BO-SiO (NBBS) glasses. The influence of Pr ions on their spectroscopic and structural characteristics in glass network is investigated. The amorphous nature of the samples has been amply verified by X-ray diffraction patterns.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
January 2025
University of Electronic Science and Technology of China, State Key Laboratory of Electronic Thin Films and Integrated Devices, No. 2006, Xiyuan Avenue, High-tech Zone (West Area), 610054, Chengdu, CHINA.
Bismuth oxide (Bi2O3) emerges as a potent catalyst for converting CO2 to formic acid (HCOOH), leveraging its abundant lattice oxygen and the high activity of its Bi-O bonds. Yet, its durability is usually impeded by the loss of lattice oxygen causing structure alteration and destabilized active bonds. Herein, we report an innovative approach via the interstitial incorporation of indium (In) into the Bi2O3, significantly enhancing bond stability and preserving lattice oxygen.
View Article and Find Full Text PDFMaterials (Basel)
December 2024
Department of Optical Science and Engineering, Shanghai Ultra-Precision Optical Manufacturing Engineering Center, Fudan University, Shanghai 200433, China.
In recent years, the fabrication of materials with large nonlinear optical coefficients and the investigation of methods to enhance nonlinear optical performance have been in the spotlight. Herein, the bismuth telluride (BiTe) thin films were prepared by radio-frequency magnetron sputtering and annealed in vacuum at various temperatures. The structural and optical properties were characterized and analyzed using X-ray diffraction, scanning electron microscopy, X-ray photoelectron spectroscopy, spectroscopic ellipsometry, and UV/VIS/NIR spectrophotometry.
View Article and Find Full Text PDFJ Phys Condens Matter
January 2025
Department of Physics, Indian Institute of Technology Delhi, Hauz Khas, New Delhi 110016, India.
Time-reversal symmetry breaking of a topological insulator phase generates zero-field edge modes which are the hallmark of the quantum anomalous Hall effect (QAHE) and of possible value for dissipation-free switching or non-reciprocal microwave devices. But present material systems exhibiting the QAHE, such as magnetically doped bismuth telluride and twisted bilayer graphene, are intrinsically unstable, limiting their scalability. A pristine magnetic oxide at the surface of a TI would leave the TI structure intact and stabilize the TI surface, but epitaxy of an oxide on the lower-melting-point chalcogenide presents a particular challenge.
View Article and Find Full Text PDFAdv Mater
December 2024
Institute of Physics (IA), RWTH Aachen University, Sommerfeldstraße 14, 52074, Aachen, Germany.
A systematic study of the impact of film thickness on the properties of thin Bi films is presented. To this end, epitaxial films of high quality have been grown on a Si (111) substrate with thicknesses ranging from 1.9 to 29.
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