Magnesium has attracted much attention as a class of biodegradable metallic biomaterials. In this study, a silicate electrolyte-based micro-arc oxidation (MAO) treatment was adopted to prepare forsterite-containing MAO coatings on a ZK60 magnesium alloy in order to decrease the degradation rate and increase the biological property of the alloy. Four anodization voltages were chosen to prepare the MAO coatings. The cell experiment showed a cytotoxicity of grade 0 for the MAO-coated alloy to L929 cells and the hemolytic ratio was dramatically decreased for the MAO-coated alloy compared with the bare one. The corrosion resistance and the degradation behavior of the MAO-coated ZK60 alloy were studied using drop tests, electrochemical measurements and immersion tests. The results indicate that the MAO coating could effectively decrease the initial degradation rate of the alloy. The corrosion resistance of MAO coating was increased with the elevation of the preparation voltage. A degradation model for ZK60 alloy with a forsterite-containing MAO coating was proposed. Based on the model, the MAO-coated alloy experiences destruction and restoration simultaneously, and the coating fails in a peeling-off mode.
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http://dx.doi.org/10.1016/j.actbio.2012.12.016 | DOI Listing |
ACS Omega
November 2024
Department of Orthopaedics, Affiliated Xinhua Hospital of Dalian University, Dalian 116001, China.
Magnesium (Mg) alloy scaffolds demonstrate promising potential for clinical applications in the repair of segmental bone defects. However, the specific mechanisms of osteoconduction and osteoinduction facilitated by these scaffolds themselves during the bone reconstruction process remain inadequately defined. This investigation systematically assesses the properties of MAO-coated Mg base implants both in vitro and in vivo.
View Article and Find Full Text PDFJ Colloid Interface Sci
November 2023
College of Materials Science and Engineering, Shandong University of Science and Technology, Qingdao 266590, China.
Materials (Basel)
November 2022
National Key Laboratory for Remanufacturing of China, Beijing 100072, China.
The early-stage (1 h) corrosion behavior of AZ91 alloy before and after microarc oxidation treatment in a 3.5% NaCl solution was revealed using open circuit potential, potentiodynamic polarization, electrochemical impedance spectroscopy, and the observations of corroded surfaces at different immersion time (5, 25 and 45 min). The coating offers excellent corrosion resistance for the substrate for 1 h immersion corrosion by serving as a physical barrier.
View Article and Find Full Text PDFBioinorg Chem Appl
March 2022
The Conversationalist Club, School of Stomatology, Shandong First Medical University and Shandong Academy of Medical Sciences, Tai'an 271016, Shandong, China.
Magnesium alloys have great application prospects as ideal bone implant materials. However, their poor corrosion resistance limits their clinical orthopedic application. Surface modification promotes the corrosion resistance of magnesium.
View Article and Find Full Text PDFInt J Mol Sci
April 2021
Combination Medical Device Technology Division, Medical Devices R&D Service Department, Metal Industries Research & Development Centre, Kaohsiung 802, Taiwan.
Micro arc oxidation (MAO) is a prominent surface treatment to form bioceramic coating layers with beneficial physical, chemical, and biological properties on the metal substrates for biomaterial applications. In this study, MAO treatment has been performed to modify the surface characteristics of AZ31 Mg alloy to enhance the biocompatibility and corrosion resistance for implant applications by using an electrolytic mixture of Ca(PO) and CHNO (EDTA) in the solutions. For this purpose, the calcium phosphate (Ca-P) containing thin film was successfully fabricated on the surface of the implant material.
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