AI Article Synopsis

  • The rise in bioethanol and biodiesel production has led to large amounts of crude glycerol, creating a need to repurpose this waste effectively.
  • One potential solution is to convert crude glycerol into a biopolymer by manipulating microbial communities using a feast-famine strategy.
  • Research shows that while lowering oxygen supply during polymer production doesn't change glycerol distribution, limiting oxygen during the enrichment phase promotes polyglucose over PHA formation.

Article Abstract

The increasing production of bioethanol and biodiesel has resulted in the generation of a massive amount of crude glycerol, inducing the need for effective valorization of these waste streams. One of the valorization options could be through conversion of crude glycerol into a biopolymer using microbial community engineering in a feast-famine process. A complicating factor in the production of biopolymers from glycerol encountered in previous works is that two different types of polymers can be formed; polyhydroxyalkanoate (PHA) and polyglucose. Here we describe the effect of limiting the oxygen supply rate on the polymer distribution with the aim of defining the conditions that favour the conversion of glycerol in one single polymer. The decrease of oxygen supply rate during the biopolymer maximization step did not influence glycerol partitioning among PHA and polyglucose, but oxygen limitation during the community enrichment step favoured polyglucose storage over PHA.

Download full-text PDF

Source
http://dx.doi.org/10.1016/j.watres.2012.11.039DOI Listing

Publication Analysis

Top Keywords

oxygen limitation
8
crude glycerol
8
pha polyglucose
8
oxygen supply
8
supply rate
8
glycerol
5
impact oxygen
4
limitation glycerol-based
4
glycerol-based biopolymer
4
biopolymer production
4

Similar Publications

Development of optical microneedle-lens array for photodynamic therapy.

Biomed Microdevices

January 2025

Institute of Industrial Science, The University of Tokyo, Meguro-Ku, 153-8505, Tokyo, Japan.

Recently, photodynamic therapy (PDT) which involves a photosensitizer (PS), a special drug activated by light, and light irradiation has been widely used in treating various skin diseases such as port-wine stain as well as cancers such as melanoma and non-melanoma skin cancers. PDT comprises two general steps: the introduction of PS into the body or a specific spot to be treated, and the irradiation process using a light source with a specific wavelength to excite the PS. Although PDT is gaining great attention owing to its potential as a targeted approach in the treatment of skin cancers, several limitations still exist for practical use.

View Article and Find Full Text PDF

Electrocatalysis: From Planar Surfaces to Nanostructured Interfaces.

Chem Rev

January 2025

Department of Chemical & Biomolecular Engineering, University of California, Irvine, California 92697, United States.

The reactions critical for the energy transition center on the chemistry of hydrogen, oxygen, carbon, and the heterogeneous catalyst surfaces that make up electrochemical energy conversion systems. Together, the surface-adsorbate interactions constitute the electrochemical interphase and define reaction kinetics of many clean energy technologies. Practical devices introduce high levels of complexity where surface roughness, structure, composition, and morphology combine with electrolyte, pH, diffusion, and system level limitations to challenge our ability to deconvolute underlying phenomena.

View Article and Find Full Text PDF

In nature, environmental conditions strongly fluctuate, frequently subjecting plants to periods of immediate photo-oxidative stress. The small molecule ascorbate allows plants to cope with such stress conditions. Ascorbate scavenges reactive oxygen species and enables the rapid and full induction of photoprotective non-photochemical quenching (NPQ).

View Article and Find Full Text PDF

Electrochemical 5-hydroxymethylfurfural (HMF) oxidation reaction (HMFOR) offers a promising route to transform biomass into value-added chemicals. However, the competing oxygen evolution reaction (OER) greatly limits the HMFOR selectivity. Herein, we report a facile doping strategy to engineer oxygen intermediates adsorption on amorphous NiFe alloys to boost highly selective electrochemical HMF oxidation to produce 2,5-furandicarboxylic acid (FDCA), among which, amorphous Mn-doped NiFeB alloy displays a low HMFOR onset potential of 1.

View Article and Find Full Text PDF

Nanoclay-Mediated Crystal-Phase Engineering in Biofunctions to Balance Antibacteriality and Cytotoxicity.

Nano Lett

January 2025

Engineering Research Center of Nano-Geomaterials of Ministry of Education, China University of Geosciences, Wuhan 430074, China.

The crystalline phase of metal oxides is a key determinant of the properties and functions of the nanomaterials. Traditional approaches have focused on replicating bulk-phase structures, with limited exploration of phase diversity due to challenges in controlling the crystal morphology. Here, we introduce a nanoclay-mediated strategy for crystal-phase engineering, using talc to modulate the morphology and phase of manganese oxide (MnOx) nanoparticles.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!