A mixture of two smectic liquid crystals was doped with harvested ferroelectric barium titanate nanoparticles and investigated with wide- and small-angle X-ray scattering during cooling from the isotropic phase. A decrease in the isotropic to nematic and in the nematic to partially bilayer smectic-A(d) (SmA(d)) phase transition temperatures was observed accompanied by an increase of the layer spacing in the SmA(d) phase.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1021/jp310624c | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Formation of the rosette-like starch with enhanced V-type crystallization via modified solvent-shifting method.
Carbohydr Polym
March 2025
Key Laboratory of Jianghuai Agricultural Product Fine Processing and Resource Utilization, Ministry of Agriculture and Rural Affairs, Anhui Engineering Research Center for High Value Utilization of Characteristic Agricultural Products, School of Tea & Food Science and Technology, Anhui Agricultural University, Hefei 230036, China. Electronic address:
This research investigated the effect modified solvent-shifting method on the formation, ordered structure, and morphology of V-type starch. Ionic liquid (IL) dissolution and hot ethanol aqueous incubation in gradient concentrations from 30 % to 80 % (v/v) were applied to optimize the relative crystallinity of V-type starch. The results showed that this new method worked in producing V-type conformation, and higher ethanol concentration tended to yield V-type starch with higher crystallinity and more disk-like shape structure within the ethanol range of 30-50 % (v/v).
View Article and Find Full Text PDFFull-Spectrum Mechanochromic Photonic Films with Large Interparticle Distance.
Adv Sci (Weinh)
January 2025
Department of Chemical and Biomolecular Engineering, Korea Advanced Institute of Science and Technology (KAIST), Daejeon, 34141, Republic of Korea.
Non-close-packed crystalline arrays of colloidal particles in an elastic matrix exhibit mechanochromism. However, small interparticle distances often limit the range of reversible color shifts and reduce reflectivity during a blueshift. A straightforward, reproducible strategy using matrix swelling to increase interparticle distance and improve mechanochromic performance is presented.
View Article and Find Full Text PDFExceptionally large fluctuations in orientational order: The lessons of large-deviation theory for liquid crystalline systems.
J Chem Phys
January 2025
Department of Chemistry, Brown University, Providence, Rhode Island 02912, USA.
How condensed-matter simulations depend on the number of molecules being simulated (N) is sometimes itself a valuable piece of information. Liquid crystals provide a case in point. Light scattering and 2d-IR experiments on isotropic-phase samples display increasingly large orientational fluctuations ("pseudo-nematic domains") as the samples approach their nematic phase.
View Article and Find Full Text PDFUnlocking Sulfide Solid-State Battery Longevity by the Paradigm of Dual-Functional Plastic Crystal.
ACS Nano
January 2025
Department of Chemistry, Collaborative Innovation Center of Chemistry for Energy Materials, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Institute of New Energy, Fudan University, Shanghai 200438, China.
The utilization of sulfide-based solid electrolytes represents an attractive avenue for high safety and energy density all-solid-state batteries. However, the potential has been impeded by electrochemical and mechanical stability at the interface of oxide cathodes. Plastic crystals, a class of organic materials exhibiting remarkable elasticity, chemical stability, and ionic conductivity, have previously been underutilized due to their susceptibility to dissolution in liquid electrolytes.
View Article and Find Full Text PDFUltrasonic Effect on the Growth of Crystals from Aqueous Electrolyte Solutions on Polymer Substrates: The Role of Isotopic Composition of Liquid.
Polymers (Basel)
December 2024
Chemistry Department, Lomonosov Moscow State University, Leninskie Gory, 1/3, Moscow 119991, Russia.
The peculiarities of the crystal formation from supersaturated aqueous solutions of CuSO on polymer substrates were studied using X-ray diffractometry. During the crystal formation, the test solutions were irradiated with one or two counter-propagating ultrasonic beams. Test solutions were prepared using natural deionized water with a deuterium content of 157 ± 1 ppm.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!