In the article the basic problems of harmonization of domestic regulatory framework of air pollution with the WHO recommendations and normative values adopted in the EU, U.S. and other countries are considered. The important role of health risk analysis methodology in the process of harmonization of regulation and control of air quality has been pointed out. The necessity of radical changes in the structure and content of the basic normative document GN 2.1.6.1338-03 "maximum permissible concentration (MPC) of pollutants in the air of populated areas" has been shown. The algorithm of the procedure that justifies the new list of normative values in the air harmonized with international recommendations and standards of developed countries has been proposed.
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