Spin wave excitations in AFe1.5Se2 (A = K, Tl): analytical study.

J Phys Condens Matter

Department of Physics, Renmin University of China, Beijing 100872, People's Republic of China.

Published: January 2013

By generalizing the equation of motion method, we can analytically solve the spin wave excitations for the intercalated ternary iron-selenide AFe(1.5)Se(2) (A = K, Tl) in a complex 4 × 2 collinear antiferromagnetic order. It is found that there are one acoustic branch (gapless Goldstone mode) and two gapful optical branches of spin wave excitations with each in double degeneracy. By examining the non-imaginary excitation frequency condition, we can determine the corresponding phase boundary. The exchange couplings between Fe moments in AFe(1.5)Se(2) are derived based on the first-principles total energy calculations. The Fe spin is found to be S = 3/2 through computing the antiferromagnetic quantum fluctuation. It is also found that a very small spin-orientation anisotropy can remarkably suppress the antiferromagnetic quantum fluctuation. The spin dynamical structure factors are calculated and discussed in association with neutron inelastic scattering experiment.

Download full-text PDF

Source
http://dx.doi.org/10.1088/0953-8984/25/3/036004DOI Listing

Publication Analysis

Top Keywords

spin wave
12
wave excitations
12
antiferromagnetic quantum
8
quantum fluctuation
8
spin
5
excitations afe15se2
4
afe15se2 analytical
4
analytical study
4
study generalizing
4
generalizing equation
4

Similar Publications

We investigate the effect of focused-ion-beam (FIB) irradiation on spin waves with sub-micron wavelengths in Yttrium-Iron-Garnet (YIG) films. Time-resolved scanning transmission X-ray (TR-STXM) microscopy was used to image the spin waves in irradiated regions and deduce corresponding changes in the magnetic parameters of the film. We find that the changes of Gairradiation can be understood by assuming a few percent change in the effective magnetizationof the film due to a trade-off between changes in anisotropy and effective film thickness.

View Article and Find Full Text PDF

Modulating Electronic Spin State of Perovskite Fluoride by Ni─F─Mn Bond Activating the Dynamic Site of Oxygen Reduction Reaction.

Small

January 2025

Beijing Key Laboratory of Energy Conversion and Storage Materials, College of Chemistry, Beijing Normal University, Beijing, 100875, P. R. China.

Establishing the relationship between catalytic performance and material structure is crucial for developing design principles for highly active catalysts. Herein, a type of perovskite fluoride, NHMnF, which owns strong-field coordination including fluorine and ammonia, is in situ grown on carbon nanotubes (CNTs) and used as a model structure to study and improve the intrinsic catalytic activity through heteroatom doping strategies. This approach optimizes spin-dependent orbital interactions to alter the charge transfer between the catalyst and reactants.

View Article and Find Full Text PDF

Densely populated macrocyclic dicobalt sites in ladder polymers for low-overpotential oxygen reduction catalysis.

Nat Commun

January 2025

College of Polymer Science and Engineering, State Key Laboratory of Polymer Materials Engineering, Sichuan University, 610065 Chengdu, China.

Dual-atom catalysts featuring synergetic dinuclear active sites, have the potential of breaking the linear scaling relationship of the well-established single-atom catalysts for oxygen reduction reaction; however, the design of dual-atom catalysts with rationalized local microenvironment for high activity and selectivity remains a great challenge. Here we design a bisalphen ladder polymer with well-defined densely populated binuclear cobalt sites on Ketjenblack substrates. The strong electron coupling effect between the fully-conjugated ladder structure and carbon substrates enhances the electron transfer between the cobalt center and oxygen intermediates, inducing the low-to-high spin transition for the 3d electron of Co(II).

View Article and Find Full Text PDF

Spin Hall nano-oscillators convert DC to magnetic auto-oscillations in the microwave regime. Current research on these devices is dedicated to creating next-generation energy-efficient hardware for communication technologies. Despite intensive research on magnetic auto-oscillations within the past decade, the nanoscale mapping of those dynamics remained a challenge.

View Article and Find Full Text PDF

Triplet-triplet energy transfer (TEnT) is of particular interest in various photochemical, photobiological, and energy science processes. It involves the exchange of spin and energy of electrons between two molecular fragments. Here, quasi-diabatic self-consistent field solutions were used to obtain the diabatic states involved in TEnT.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!