Organic semiconductors might enable new applications in low-cost, light-weight, flexible electronics. To build a solid foundation for these technologies, more fundamental studies of electro-mechanical properties of various types of organic semiconductors are necessary. Here we perform basic studies of charge transport in highly crystalline solution-processed organic semiconductors as a function of applied mechanical strain. As a test bed, we use small molecules crystallized on thin plastic sheets, resulting in high-performance flexible field-effect transistors. These devices can be bent multiple times without degradation to a radius as small as ~200 μm, demonstrating that crystalline solution-processed organic semiconductors are intrinsically highly flexible. This study of electro-mechanical properties suggests that solution-processable organic semiconductors are suitable for applications in flexible electronics, provided that integration with other important technological advances, such as device scalability and low-voltage operation, is achieved in the future.
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http://dx.doi.org/10.1038/ncomms2263 | DOI Listing |
Sensors (Basel)
December 2024
Shandong Provincial Key Laboratory of Monocrystalline Silicon Semiconductor Materials and Technology, Shandong Provincial Engineering Research Center of Organic Functional Materials and Green Low-Carbon Technology, Shandong Universities Engineering Research Center of Integrated Circuits Functional Materials and Expanded Applications, College of Chemistry and Chemical Engineering, Dezhou University, Dezhou 253023, China.
In this paper, a novel molecularly imprinted polymer membrane modified glassy carbon electrode for electrochemical sensors (MIP-OH-MWCNTs-GCE) for epinephrine (EP) was successfully prepared by a gel-sol method using an optimized functional monomer oligosilsesquioxane-AlO sol-ITO composite sol (ITO-POSS-AlO). Hydroxylated multi-walled carbon nanotubes (OH-MWCNTs) were introduced during the modification of the electrodes, and the electrochemical behavior of EP on the molecularly imprinted electrochemical sensors was probed by the differential pulse velocity (DPV) method. The experimental conditions were optimized.
View Article and Find Full Text PDFMaterials (Basel)
January 2025
Key Laboratory of Applied Surface and Colloid Chemistry, National Ministry of Education, Shaanxi Key Laboratory for Advanced Energy Devices, Shaanxi Engineering Laboratory for Advanced Energy Technology, School of Materials Science and Engineering, Shaanxi Normal University, Xi'an 710119, China.
Perovskite solar cells (PSCs) can utilize the residual photons from indoor light and continuously supplement the energy supply for low-power electron devices, thereby showing the great potential for sustainable energy ecosystems. However, the solution-processed perovskites suffer from serious defect stacking within crystal lattices, compromising the low-light efficiency and operational stability. In this study, we designed a multifunctional organometallic salt named sodium sulfanilate (4-ABS), containing both electron-donating amine and sulfonic acid groups to effectively passivate the positively-charged defects, like under-coordinated Pb ions and iodine vacancies.
View Article and Find Full Text PDFMaterials (Basel)
January 2025
ABB Corporate Technology Center, 13A Starowislna Str., 31-038 Krakow, Poland.
In this study, it is shown that an efficient organic optocoupler (OPC) can be fabricated using commercially available and solution-processable organic semiconductors. The transmitter is a single-active-layer organic light-emitting diode (OLED) made from a well-known polyparavinylene derivative, Super Yellow. The receiver is an organic light-emitting diode (OLSD) with a single active layer consisting of a mixture of the polymer donor PTB7-Th and the low-molecular-weight acceptor ITIC; the receiver operates without an applied reverse voltage.
View Article and Find Full Text PDFMaterials (Basel)
December 2024
Chemistry Institute, Universidad Nacional Autónoma de México, Circuito Exterior S/N, Ciudad Universitaria, Ciudad de México 04510, Mexico.
In this work, we present the green synthesis of complex - derived from β-hidroxymethylidene indanones by ultrasound, which allowed for the obtaining of compounds in a shorter time and with good yields. These organotin complexes were then doped with cobalt porphine and incorporated into a poly(3,4-ethylenedioxythiophene):poly(4-styrenesulfonate) matrix to manufacture composite semiconductor films. The semiconductor films were characterized through atomic force microscopy, examining their topography, Knoop hardness (around 17 HK), and tensile strength, which varied from 5 × 10 to 7 × 10 Pa.
View Article and Find Full Text PDFMolecules
December 2024
Institute of Chemical Technology and Engineering, Faculty of Chemical Technology, Poznan University of Technology, Berdychowo 4, 60-965 Poznan, Poland.
The concept of using polyaniline/titanium dioxide heterostructures as efficient photocatalysts is based on the synergistic effect of conducting polymer and metal oxide semiconductors. Due to inconclusive literature reports, the effect of different polyaniline/TiO ratios on photocatalytic activity under UV and visible light was investigated. In most papers, non-recommended dyes are used as model compounds to evaluate visible light activity.
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