[RhCp*(OAc)(2)(H(2)O)] [Cp* = pentamethylcyclopentadienyl] catalyzed the C-H bond amidation of ferrocenes possessing directing groups with isocyanates in the presence of 2 equiv/Rh of HBF(4)·OEt(2). A variety of disubstituted ferrocenes were prepared in high yields, or excellent diastereoselectivities.
Download full-text PDF |
Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3511021 | PMC |
| http://dx.doi.org/10.3762/bjoc.8.212 | DOI Listing |
Publication Analysis
Top Keywords
c-h bond
8
bond amidation
8
amidation ferrocenes
8
rhiii-catalyzed directed
4
directed c-h
4
ferrocenes isocyanates
4
isocyanates [rhcp*oac2h2o]
4
[rhcp*oac2h2o] [cp*
4
[cp* pentamethylcyclopentadienyl]
4
pentamethylcyclopentadienyl] catalyzed
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!