A variety of nanoscale photonic, mechanical, electronic, and optoelectronic devices require scalable thin film fabrication. Typically, the device layer is defined by thin film deposition on a substrate of a different material, and optical or electrical isolation is provided by the material properties of the substrate or by removal of the substrate. For a number of materials this planar approach is not feasible, and new fabrication techniques are required to realize complex nanoscale devices. Here, we report a three-dimensional fabrication technique based on anisotropic plasma etching at an oblique angle to the sample surface. As a proof of concept, this angled-etching methodology is used to fabricate free-standing nanoscale components in bulk single-crystal diamond, including nanobeam mechanical resonators, optical waveguides, and photonic crystal and microdisk cavities. Potential applications of the fabricated prototypes range from classical and quantum photonic devices to nanomechanical-based sensors and actuators.
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http://dx.doi.org/10.1021/nl302541e | DOI Listing |
Materials (Basel)
December 2024
College of Mechanical Engineering, Zhejiang University of Technology, Hangzhou 310023, China.
As an environment-friendly material, graphene oxide nanosheet can effectively improve the polishing surface quality of single crystal diamond workpieces. However, the lubricating and chemical effects of graphene oxide nanosheets have an uncertain impact on the polishing material removal rate. In this paper, the graphene oxide-enhanced hybrid slurry was prepared with good stability.
View Article and Find Full Text PDFRev Sci Instrum
January 2025
Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, USA.
The Particle Time of Flight (PTOF) diagnostic is a chemical vapor deposition diamond-based detector and is the only diagnostic for measuring nuclear bang times of low yield (<1013) shots on the National Ignition Facility. Recently, a comprehensive study of detector impulse responses revealed certain detectors with very fast and consistent impulse responses with a rise time of <50 ps, enabling low yield burn history measurements. At the current standoff of 50 cm, this measurement is possible with fast 14 MeV neutrons from deuterium-tritium (DT) fusion plasmas.
View Article and Find Full Text PDFAdv Sci (Weinh)
December 2024
Department of Chemistry and Chemical Engineering, Chalmers University of Technology, Göteborg, SE-412 96, Sweden.
Carbazole-based self-assembled monolayer (SAM) materials as hole transport layers (HTL) have led organic solar cells (OSCs) to state-of-the-art photovoltaic performance. Nonetheless, the impact of the alkyl spacer length of SAMs remains inadequately understood. To improve the knowledge, four dichloride-substituted carbazole-based SAMs (from 2Cl-2PACz to 2Cl-5PACz) with spacer lengths of 2-5 carbon atoms is developed.
View Article and Find Full Text PDFChem Commun (Camb)
December 2024
Goethe University Frankfurt, Institute of Geosciences, Altenhöferallee 1, 60438 Frankfurt, Germany.
We have synthesized the first hydrous sp-carbonate by laser-heating Ba[CO], CO and HO in a diamond anvil cell at 40(3) GPa. The crystal structure of Ba[HCO][HCO][HCO][HCO] was determined by synchrotron single crystal X-ray diffraction. The experiments were complemented by DFT-based calculations.
View Article and Find Full Text PDFIUCrJ
January 2025
Department of Chemistry, Biological and Chemical Research Centre, University of Warsaw, Żwirki i Wigury 101, Warszawa, 02-089, Poland.
High-resolution single-crystal X-ray diffraction experiments on ZnSiO(OH)·HO hemimorphite were conducted at high pressure using diamond anvil cells at several different synchrotron facilities (ESRF, Elettra, DESY). Experimental data confirmed the existence of a previously reported phase transition and revealed the exact nature of the incommensurate modulation. We report the incommensurately modulated structure described in the (3+1)D space group Pnn2(0, β, 0)000.
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