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Analytical protocol for measuring micro-molar quantities of sulfur volatile species in experimental high pressure and temperature fluids.
Commun Chem
January 2025
Dipartimento di Scienze Della Terra, Università Degli Studi di Milano, via Mangiagalli 34, I-20133, Milano, Italy.
Validating thermodynamic models is essential in experimental geosciences for exploring increasingly complex systems and developing analytical protocols. However, investigating solid-fluid equilibria in mm-sized experimental capsules poses several challenges, particularly in sulfur-bearing chemical systems. These include maintaining bulk fluid composition and performing quantitative analysis with extremely low amounts of synthesized fluid.
View Article and Find Full Text PDFPreparation of Polyaniline Modified Cellulose Filter Paper and Its Application in Detecting 23 Per- and Polyfluoroalkyl Substances.
J Sep Sci
January 2025
Guangzhou Institute of Chemistry, Chinese Academy of Sciences, Guangzhou, China.
Per- and polyfluoroalkyl substances (PFAS) are a widely used class of synthetic chemicals that pose a significant global environmental and health threat due to their persistent and bioaccumulation toxicity caused by strong C-F bonds in their structures. PFAS usually exist in trace concentrations in environmental water bodies, which poses great challenges for environmental analysis. In this study, environmentally friendly cellulose was modified with polyaniline through in situ oxidative polymerization, and used as the filter paper for solid-phase extracting 23 PFAS in water.
View Article and Find Full Text PDFBackground: There is a lack of evidence regarding the association between plasma phenylacetylglutamine levels and lesion severity and clinical prognosis in patients with ST-segment elevation myocardial infarction (STEMI) with multivessel coronary disease (MVCD). This study aims to investigate the potential of phenylacetylglutamine as a biomarker for major adverse cardiovascular events (MACEs) of patients with STEMI and MVCD.
Methods And Results: Clinical data and blood samples were collected from 631 patients with STEMI and MVCD, who underwent primary percutaneous coronary intervention.
L. (purslane) extract ameliorates intestinal inflammation in diet-induced obese mice by inhibiting the TLR4/NF-κB signaling pathway.
Front Pharmacol
January 2025
State Key Laboratory of Quality Research in Chinese Medicine, Institute of Chinese Medical Sciences, University of Macau, Macau SAR, China.
Background: L. (purslane) is a dietary plant and a botanical drug with antioxidant, antidiabetic, and anti-inflammatory activities. However, the effects of purslane against intestinal-inflammation-associated obesity are yet to be studied.
View Article and Find Full Text PDFElucidating molecular characteristics of organic compounds during ozone micro-bubbles treatment based on GC × GC-QTOF-MS and non-targeted analysis.
J Environ Manage
January 2025
College of Environment, Hohai University, Nanjing, 210098, PR China; Suzhou Research Institute, Hohai University, Suzhou, 215100, PR China; Ministry of Education Key Laboratory of Integrated Regulation and Resource Development on Shallow Lakes, Hohai University, Nanjing, 210098, PR China. Electronic address:
The ozone micro-bubbles (OCBs) technology is increasingly gaining traction as a promising alternative method for organic compounds removal in wastewater. Nevertheless, there is a scarcity of literature addressing the molecular-level transformation of organic compounds during OCBs treatment. In this work, the secondary effluent from a wastewater treatment plant was treated with ozone milli-bubbles (OLBs) and OCBs, and the fate of organic compounds at the molecular level was investigated using comprehensive two-dimensional gas chromatography quadrupole time-of-flight mass spectrometry (GC × GC-QTOF-MS).
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