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γ-Selective directed catalytic asymmetric hydroboration of 1,1-disubstituted alkenes. | LitMetric
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γ-Selective directed catalytic asymmetric hydroboration of 1,1-disubstituted alkenes.

Sean M Smith Gia L Hoang Rhitankar Pal Mohammad O Bani Khaled Liberty S W Pelter Xiao Cheng Zeng James M Takacs

Chem Commun (Camb)

Department of Chemistry, University of Nebraska-Lincoln, Lincoln, Nebraska, USA.

Published: December 2012

Directed catalytic asymmetric hydroborations of 1,1-disubstituted alkenes afford γ-dioxaborato amides and esters in high enantiomeric purity (90-95% ee).

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 Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3601746PMC
http://dx.doi.org/10.1039/c2cc36199jDOI Listing

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